経歴

1964年早稲田大学理工学部応用化学科卒,
1969年同大学院理工学研究科博士課程修了(工学博士)
1969年早稲田大学助手
1971-1973年カナダアルバータ大学博士研究員
1975年早稲田大学助教授
1980年同学教授

1995-1997年触媒学会庶務理事, 1995-1996年石油学会庶務理事. 1977年石油学会論文賞, 1981年燃料協会進歩賞, 1992年触媒調製化学賞, 1996年触媒学会賞.

キーワード

触媒化学 / エネルギー・燃料化学 / 環境触媒化学 / 不均一系触媒作用 / メンブレンリアクター / 水素透過膜 / ゼオライト / 超伝導酸化物

Tel: 03-5286-3203

Fax: 03-3200-5349

E-mail:ekikuchiwaseda.jp

研究内容

エネルギー・燃料化学および石油化学に関連する不均一系触媒反応と触媒に関する研究．とくに，遷移金属および金属酸化物触媒と固体酸塩基触媒上での反応機構について研究している．これに関連する触媒調製化学も重要な研究課題である．具体的な反応を挙げると，炭化水素の水蒸気および炭酸ガス改質(水素および合成ガスの生成)，部分酸化，触媒燃焼，窒素酸化物の選択的還元などである．また選択的水素透過膜およびゼオライト膜の調製や，それらの触媒反応への適用(メンブレンリアクター) についても研究している．

代表論文

1. "Steam Reforming of Methanol on Ni/Al2O3 Catalyst in a Pd-membrane Reactor", Journal of the Japan Petroleum Institute, 46, 93-98 (2003)

2. "Co Cation Effects on Activity and Stability of Isolated Pd(II) Cations in Zeolite Matrices for Selective Catalytic Reduction of Nitric Oxide with Methane", Journal of Catalysis, 211, 75-84 (2002)

3. "Effect of NH4+ Exchange on Hydrophobicity and Catalytic Properties of Al free Ti-Si-beta Zeolite", Journal of Catalysis, 199, 41-47 (2001).

4. "Palladium Species in Pd/H-ZSM-5 Zeolite Catalysts for CH4-SCR", Research on Chemical Intermediates, 26, 55-60 (2000).

5. "Determination of Active Palladium Species in ZSM-5 Zeolite for Selective Reduction of Nitric Oxide with Methane", Applied Catalysis B, 23, 247-257 (1999).

6. "Role of Zeolite Structure on Reduction of NOx with Methane over In- and Pd-based Catalysts", Catalysis Today, 45, 139-145 (1998).

7. "Intrapore Catalysis in Reduction of Nitric Oxide with Methane", Catalysis Today, 42, 159-166 (1998).

8. "The Effect of Zeolite Structure on Creation of InO+ Active Sites for NOx Reduction with Methane", Microporous and Mesoporous Materials, 21, 533-540 (1998).

9. "Hydrogen-Permselective Membrane Reactors", CaTTech, 1, 67 (1997)

10. "Catalytic Properties and Crystalline Structures of Manganese-Promoted Iron Ultrafine Particles for Liquid Phase Hydrogenation of Carbon Monoxide" Applied Catalysis. A, 96, 125 (1993)

11. "Gallium Ion-exchanged Zeolite as a Selective Catalyst for Reduction of Nitric Oxide with Hydrocarbons under Oxygen-rich Conditions", Catalysis Letters, 17, 303 (1993)

12. "Hydrogen Permeable Palladium-Silver Alloy Membrane Supported on Porous Ceramics", Journal of Membrane Science, 56, 315 (1991)

13. "The Effect of Spilled-over Hydrogen on the Activity of Montmorillonite Pillared by Aluminum Oxide for Conversion of Trimethylbenzenes", Journal of Catalysis, 106, 38 (1987)

14. "Catalytic Synthesis of Hydrocarbons from Carbon Monoxide and Hydrogen on Lamellar Compound of Graphite Intercalated by Ferric Chloride", Journal of Catalysis, 57, 27 (1979)

15. "The Reaction of n-Heptane on Rhodium Catalysts in the Presence of Steam", Journal of Catalysis, 46, 382 (1977)

16. "Studies of the Enhancement of Hydrogen Adsorption during H2-O2 Titration on Supported Pt Catalysts", Journal of Catalysis, 34, 132 (1974)

17. "Hydrogenolysis and Isomerization of n-Pentane on Group�[ Transition Metals", Journal of Catalysis, 22, 226 (1971)

18. "Hydrogenolysis of n-Pentane on Nickel Catalyst", Journal of Catalysis, 15, 217(1969)